Glossary
| The penetration of substances into the bulk of a solid or liquid. | |
| ACTIVE | The amount, in weight %, of titratable surfactant in a solution or formulation. Almost every product has an active specification. |
| ACRONYMS |
1) Chemicals and Materials |
| ADDITIVE | Any material added to a base stock to change its properties, characteristics or performance. |
| ADSORPTION | The surface retention of solid, liquid or gas molecules, atoms or ions by a solid or liquid. |
| ALKANOLAMINE | An amine where some or all of the alkyl groups attached to the nitrogen contain hydroxyl functionality. For example; triethanolamine (TEA), monisopropanolamine (MIPA). |
| ALKYLATE | The product of a reaction between an olefin, such as 1-dodecene or Tetramer-M, and an aromatic hydrocarbon, such as benzene, toluene or diphenyl oxide. |
| AMPHOTERIC SURFACTANT | A surfactant in which the hydrophile has both positive and negative charges. Examples; betaines and amine oxides. (see RFF 750.10.01 - SURFACTANTS) |
| ANIONIC SURFACTANT | A surfactant in which the hydrophile is negatively charged. Examples; sulfonates and sulfates. (see RFF 750.10.01 - SURFACTANTS). |
| ANTIFOAM | An additive used to suppress the foaming characteristics of a formulation in service. |
| ANTIMICROBIAL | A chemical which either destroys or inhibits the growth of microscopic and sub-microscopic organisms. |
| ANTIWEAR ADDITIVE | Compounds which form, or react to form, thin films on highly loaded parts in operation to prevent metal to metal contact, thereby reducing friction at the point of contact. |
| BASE OIL (NAPHTHENIC) | A type of petroleum oil fluid derived from naphthenic crude oil. Contains a high degree of closed ring methylene groups. |
| BASE OIL (PARAFFINIC) | A type of petroleum oil fluid derived from paraffinic crude oil, containing a high proportion of straight chain saturated hydrocarbons. |
| BASE STOCK | The base carrier fluid, usually a refined petroleum fraction or synthetic fluid, into which additives are blended to produce finished lubricants. |
| BIOCIDE | A chemical agent which destroys microscopic and sub-microscopic organisms. |
| BRIGHT STOCK | A heavy lubricant stock with a low pour point used in finished blends to provide film strength and to reduce the amount of oil consumed. |
| BUFFER | A solution containing both a weak acid and its conjugate base which resists changes in pH brought on by addition of an acid or base to the solution. (see RFF 705.10.09 - BUFFERS) |
| BUILDER | Binds hardness ions, calcium and magnesium, to remove them from solution either as a soluble complex or as a precipitate. |
| CATIONIC SURFACTANT | A surfactant in which the hydrophile is positively charged. Examples; quaternary ammonium salts. (see RFF 750.10.01 - SURFACTANTS). |
| CHELATION | A process in which a metal ion is coordinatively bound to an organic molecule forming a heterocyclic ring. |
| CHROMATOGRAPHY | The separation of the components of a mixture by use of differences in their interactions with a stationary medium. |
| CLOUD POINT | Anionics - the temperature at which a product becomes turbid when it is cooled under specific conditions. Nonionics - the temperature at which a product becomes turbid when it is warmed - (see RFF 705.10.55 - CLOUD POINT). |
| COMBINING WEIGHT | The apparent equivalent weight of, for example, a sulfonic acid, where two or more acidic components, in this case the sulfonic acid product and sulfuric acid impurity, are present. (see RFF 705.10.51 - COMBINING WEIGHT). |
| COMBUSTIBLE LIQUID | A liquid which has a flash point above 100°F. |
| CORROSION INHIBITOR | An additive or a system used for protecting metal surfaces from chemical attack by water or other materials producing sulfides or oxides which result in metal fatigue or degradation. |
| CRITICAL MICELLE CONCENTRATION | The solution concentration of a surfactant at which micelles start to form in that solution. (see RFF 705.10.03 - SURFACE TENSION). |
| DEMULSIBILTY | A measure of a fluid’s ability to separate from water. |
| DETERGENT | A synthetic cleansing agent resembling soap in its ability to remove a soil from a surface. |
| DISPERSION | A stable distribution of fine solid particles in a liquid. |
| DuNOUY RING TENSIOMETER | A piece of equipment which measures the force required to remove a ring of precisely known dimensions from a liquid surface. This force is directly related to the surface tension of that liquid. (see RFF 705.10.03 - SURFACE TENSION). |
| EMOLLIENT | A softening agent, such as lanolin and its derivatives, for use on the skin. |
| EMULSIFIER | An additive or system which promotes a stable mixture of oils/fats in water. |
| EMULSION | A dispersion of one liquid in a second, immiscible liquid. (see RFF 705.10.07 - EMULSIONS). |
| EMULSION POLYMERIZATION | Emulsion polymerization is a heterogeneous, free-radical polymerization process in which the bulk of the polymeric product in formed inside micelles. |
| EP ADDITIVE | A lubricant additive or system which prevents sliding metal surfaces from seizing under conditions of extreme pressure and force. |
| ETHOXYLATE | Common name for a compound formed by the chemical addition of a number of molecules of ethylene oxide to an alcohol. |
| FLAMMABLE LIQUID | A liquid which has a flash point below 100°F. |
| FLASH POINT | The lowest temperature at which vapors from a volatile liquid will ignite on application of an ignition source under specified conditions. Flash point is a specification for some alkylates. |
| FLOCCULATION | The process by which small particles in a dispersion slowly aggregate (or coalesce) to form flocs. |
| FOAM | A foam is a stable, or otherwise, dispersion of a gas in a liquid. |
| FOAM BOOSTER | A substance which enhances the quality and/or longevity of a foam. |
| FORMULATION | A blend of a number of base chemicals and additives designed to accomplish a specific purpose. |
| GARDNER | A unit of color density. Measured by comparison of the material to be analyzed against standards of known intensity. (see RFF 705.10.52 - COLOR). |
| HYDROGEN BONDING | The electrostatic attraction between a hydrogen atom bearing a slight positive charge and an electronegative atom, such as oxygen, in the same (intramolecular), or a different (intermolecular) molecule. |
| HYDROPHILE-LIPOPHILE BALANCE | A measure of the relative simultaneous attraction of an surfactant to both phases of an emulsion. |
| HYDROPHILE | A material having an affinity for, attracting, adsorbing or absorbing water. The opposite of hydrophobe. |
| HYDROPHOBE | A material lacking affinity for, repelling, failing to adsorb or absorb water. The opposite of hydrophile. |
| HYDROTROPE | A substance, such as sodium xylene sulfonate, which increases the aqueous solubility of surfactants and other substances. Hydrotropes are sometimes used to reduce a systems viscosity. (see RFF 705.10.08 - HYDROTROPES). |
| HYDROXYL NUMBER | A measure of the hydroxyl content of ethoxylates. Measured titrimetrically. Usually used for molecular weight determinations. |
| KLETT | A unit of color density. Measured by the light absorption of a clear solution using a Klett-Summerson photoelectric colorimeter. (see RFF 705.10.52 - COLOR). |
| KRAFFT POINT | The temperature at which the solubility of an ionic surfactant becomes equal to the critical micelle concentration. (see RFF 705.10.55 - KRAFFT POINT). |
| LYOPHILE | A material having an affinity for, attracting, adsorbing or absorbing oil. The opposite of lyophobe. |
| LYOPHOBE | A material lacking affinity for, repelling, failing to adsorb or absorb oil. The opposite of lyophile. |
| MICELLE | Colloidal aggregates of surfactant molecules. Micelles first form in a surfactant solution at a well-defined concentration known as the Critical Micelle Concentration. (see RFF 705.10.03 - MICELLES). |
| MONOMER | A simple molecule, such as styrene, which has the ability to combine with a number of like or unlike molecules to form a polymer - polystyrene or styrene/butadiene rubber. |
| NEUTRALIZATION | The process by which acids, such as sulfonic or sulfuric acids, are reacted with bases, such as sodium hydroxide or triethanolamine, to give a salt, such as a sulfonate or sulfate. |
| NONIONIC SURFACTANT | A surfactant in which the hydrophile is uncharged. Examples; ethoxylated alcohols and phenols. (see RFF 750.10.01 - SURFACTANTS). |
| OLEFIN | A hydrocarbon containing a carbon-carbon double bond. Olefins are also known as alkenes. |
| OLIGOMER | A polymer made up with two, three or four monomer units, for example propylene tetramer. |
| OPACIFIER | A substance, such as fatty acid esters, which, when added to a clear formulation, renders that formulation opaque - similar to pearlizer. |
| OXIDATION | A chemical reaction which increases the oxygen content of a compound. In metal-working, oxidation usually leads to viscosity increases and deposit formation. |
| PEARLIZER | A substance, such as glycol distearate (EGDS), which, when added to a formulation, imparts an opalescent finish to that formulation. |
| PETROLEUM ETHER EXTRACT (PEE) | see - UNREACTED |
| pH | A measure of the acidity or basicity of a solution. Mathematically the pH is -log10 of the hydrogen ion concentration of the solution. Under normal circumstances, the possible range of values is 0 -14. A pH < 7 indicates acidity, > 7 indicates basicity. pH is a common specification for water soluble materials. |
| PRESERVATIVE | A chemical added to a product to inhibit the growth of bacteria. |
| RUST PREVENTATIVE | A compound or formulated system used for coating metal surfaces to produce a film which protects against rust formation |
| SALT THICKENING | The increase in viscosity of a micellar solution on the addition of an electrolyte, such as sodium chloride. This is a similar effect to that seen with THICKENERS, but by a different mechanism. |
| SOIL | In the surfactant world - any material, solid, liquid or paste contaminant adsorbed onto a substrate. |
| SOLIDS | The amount, in weight %, of non-volatile material in a solution or formulation. Solids content is a specification in a number of blends and formulations. |
| SOLUBLE OIL | An oil that readily forms a stable emulsion or colloidal suspension in water. |
| SPECIFIC GRAVITY | The ratio of the density of a material to that of a standard material at a specified temperature, usually water at 4°C. |
| SULFATION | The process by which an alcohol, such as lauryl alcohol, is reacted with sulfur trioxide (or chlorosulfonic acid) to give an alkyl sulfuric acid. |
| SULFONATION | The process by which a material such as an alkylate is reacted with sulfur trioxide to give a sulfonic acid. |
| SURFACE TENSION | The force acting on the surface of a liquid, tending to minimize the area of that surface. (see RFF 705.10.03 - SURFACE TENSION). |
| SURFACTANT | A material which possesses the ability to radically alter the free energy of a liquid surface or interface when present in the system at low concentrations. The word “surfactant” is a contraction of the term “surface active agent.” (see RFF 750.10.01 - SURFACTANTS) |
| THICKENER | A substance, such as Xanthan Gum, which, when added in low concentrations to a fluid, raises the viscosity of that fluid. (see also SALT THICKENING). |
| UNREACTED (OIL) | Unreacted is an organic substance present in small amounts in products generally consisting of sulf(on)ation feedstock, for example an alkylate or fatty alcohol or reaction by-products, for example, sulfones. (see RFF 705.10.53 - UNREACTED OIL). |
| UNSULFATED MATTER | see - UNREACTED |
| VAPOR PRESSURE | The pressure of vapor above a liquid or solid surface which is in equilibrium with that liquid or solid. |
| VISCOSITY | The resistance the a liquid (or gaseous) system offers to flow when it is subjected to shear stress. Viscosity is a specification for a number of oils, solutions and blends. |
| VISCOSITY INDEX | The relationship of viscosity to temperature of a fluid. High viscosity index fluids will display less change in viscosity with temperature. |
| WETTING | The coating of a contact surface with an adherent film of liquid. |

